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本文以亚硫酸盐和硫酸铜制备的氧化亚铜为样品,用Kissinger法和FWO法研究了氧化亚铜的氧化动力学行为,结果表明:氧化亚铜氧化反应生成氧化铜的表观活化能E=174.52 kJ.mol-1,指前因子lnA=195.526 8,相对应的反应级数n=0.99。
Abstract：The sample of cuprous oxide was prepared from CuSO4 and NaSO3.The oxidation kinetic parameters of cuprous oxide were studied by Kissinger method.The results showed that the activation energy,the pre-exponential factor,the reaction order of the oxidation of cuprous oxide is 174.956 kJ·mol-1,7.715×1012,0.99 respectively.
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基本信息:
DOI：10.16441/j.cnki.hdxb.2011.z1.020
中图分类号:O643.1
引用信息:
[1]张雅栋,高荣杰,翟纪伟,等.氧化亚铜的氧化动力学[J].中国海洋大学学报(自然科学版),2011,41(Z1):129-132.DOI:10.16441/j.cnki.hdxb.2011.z1.020.
基金信息:
山东省自然科学基金项目(Y2007F43)资助
2011-01-15
2011-01-15