基于菲、蒽化合物的油种鉴别诊断比值的抗风化能力研究Weathering Resistance Ability of Diagnostic Ratios Based on Phenanthrenes and Anthracenes for Oil Species Identification
张海江,韩彬,王传远,尹晓楠,王江涛
摘要(Abstract):
定期采集青岛"11.22"中石化东黄输油管道泄漏爆炸事故岸滩溢油样品,使用气相色谱/质谱联用仪进行检测,考察了自然风化条件下基于菲、蒽化合物的油种鉴别诊断比值的中长期稳定性。结果表明:在为期142d的自然风化过程中,诊断比值2-甲基蒽/2-甲基菲、2-甲基蒽/9-甲基菲、2-甲基蒽/(3-+2-+9-+1-)甲基菲、(3-+2-)/(9-+1-)甲基菲受自然风化作用影响较小,相对标准偏差RSD%<5;2-甲基蒽/3-甲基菲、2-甲基蒽/1-甲基菲、2-甲基蒽/(9-+1-)甲基菲、2-甲基蒽/(3-+2-)甲基菲、蒽/(蒽+菲)受到一定程度的自然风化作用影响(5
关键词(KeyWords):
自然风化;油种鉴别;诊断比值;抗风化能力
基金项目(Foundation):
海洋公益性行业科研专项项目(201505034);;
国家重点研发计划项目(2016YFC1402101)资助~~
作者(Author):
张海江,韩彬,王传远,尹晓楠,王江涛
DOI:
10.16441/j.cnki.hdxb.20170051
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