李先国,阎国芳,周晓,虢新运,王岩,刘金燕

• 1:中国海洋大学海洋化学理论与工程技术教育部重点实验室
• 2:青岛市产品质量监督检验所
• 3:国家质量监督检验检疫总局

摘要(Abstract)：

建立了用固相萃取-高效液相色谱-荧光检测法测定海水中多环芳烃的方法,优化了色谱条件和萃取条件。除苊不能用荧光检测器检出外,其余15种多环芳烃的空白加标回收率在64.5%(苯并[g,h,i],茚并[1,2,3-cd]芘)～88.7%(苯并[a]蒽)之间,相对标准偏差(n=5)为4.9%(荧蒽,苯并[b]荧蒽)～11.1%(苯并[g,h,i],茚并[1,2,3-cd]芘),方法的检出限在0.72(蒽)～14.10 ng/L(荧蒽)之间,基本上达到了痕量分析的要求。利用该方法测得青岛湾表层海水中多环芳烃的浓度在0.125(苯并[k]荧蒽)～25.996 ng/L(萘)之间,但苯并[a]芘未检出。

关键词(KeyWords)： 固相萃取;高效液相色谱;海水;多环芳烃测定

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(20775074)资助

作者(Author): 李先国,阎国芳,周晓,虢新运,王岩,刘金燕

DOI: 10.16441/j.cnki.hdxb.2009.05.046

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