仿鲨鱼电场探测镍酸钐膜电极海水稳定性及电化学性能分析Analysis of Seawater Stability and Electrochemical Properties of Perovskite Nickelate Film Electrode of Shark-Mimetic Detection for Ocean Electric Field
胡承儒,付玉彬,韩永康,孙久哲
摘要(Abstract):
本文使用两种厚度镍酸钐膜(30、60 nm),在实海长期浸泡,研究实际稳定性和电化学性能。结果表明镍酸钐膜在海水中长期浸泡,局部有溶蚀现象,对应样品存在失重。循环伏安曲线存在明显的氧化还原峰,30 nm SNO样品氧化还原峰与60 nm SNO样品出峰位置相差约0.2 V,30 nm SNO样品比60 nm SNO样品的交换电流密度大一个数量级,可知30 nm SNO样品电子转移活性更高,更容易发生氧化还原反应。交流阻抗测试结果表明样品存在巨大的电阻变化,30 nm SNO样品比60 nm SNO样品反应更快,电子转移电阻更小。配对电极电场响应测试结果表明响应波形不规则、且漂移较大,两种厚度样品均未能正常响应。
关键词(KeyWords): 海洋电场测试;镍酸钐纳米膜;电化学性能;化学稳定性;膜电阻变化
基金项目(Foundation): 国防科技创新特区项目(18-H863-05-2T-002-013-01)资助~~
作者(Author): 胡承儒,付玉彬,韩永康,孙久哲
DOI: 10.16441/j.cnki.hdxb.20220154
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