冷涛,王立群,于良民,张志明

• 1:中国海洋大学海洋化学理论与工程技术教育部重点实验室

摘要(Abstract)：

改进了离子液体/水界面聚合方法,将苯胺和掺杂剂溶解在离子液体相中,成功合成了对甲苯磺酸聚苯胺(PANI-TSA)微/纳米纤维和盐酸掺杂聚苯胺(PANI-HCl)微/纳米纤维,其平均直径分别为488和183nm。考察了掺杂剂的浓度对聚苯胺微/纳米纤维的形貌及电导率的影响。实验发现离子液体相中掺杂剂的浓度越高,合成出的聚苯胺微纳米纤维直径越小,以PANI-TSA为例,当p-TSA的浓度由0.005mol·L~(-1)增加到0.05mol·L~(-1)时,PANI-TSA的平均直径从488nm逐渐减小到183nm,相应其室温电导率由1.6×10~(-3)S/cm增加到4.9×10~(-3)S/cm,表现出尺寸效应。

关键词(KeyWords)： 聚苯胺微/纳米纤维;离子液体;界面聚合;过硫酸铵

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(41476059)资助~~

作者(Author): 冷涛,王立群,于良民,张志明

DOI: 10.16441/j.cnki.hdxb.20150083

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