宋维星,周衍平,陈旭,李恩,季军远

• 1:中国海洋大学环境科学与工程学院
• 2:齐鲁交通服务开发集团有限公司
• 3:海军后勤部专项工程建设办公室

摘要(Abstract)：

以新型间歇增氧垂直流人工湿地系统为研究对象,采用中心复合设计响应曲面法优化垂直流人工湿地脱氮处理过程中曝气工艺参数并预测其脱氮效能。以曝气量、曝停比、曝停周期为间歇曝气影响因素,分别以人工湿地氨氮去除率和总氮去除率为响应值建立垂直流人工湿地氨氮去除率和总氮去除率的二次回归模型,通过假设检验(F-test),模型均非常显著且具有较好的相关性。间歇增氧垂直流人工湿地脱氮处理中曝气量、曝停比为对氨氮去除影响极显著的曝气参数,通过影响因子主次分析,曝气量、曝停比、曝停周期对氨氮去除率的影响顺序是:曝停比>曝气量>曝停周期;曝停周期为对总氮去除具有极显著影响的曝气参数,通过影响因子主次分析,曝气量、曝停比、曝停周期对TN去除率的影响顺序是:曝停周期>曝气量>曝停比。模型预测氨氮与总氮去除率的最佳曝气参数分别为:曝气量2 m~3/h、曝停比0.25、曝停周期12 h、曝气量2 m~3/h、曝停比0.25、曝停周期6 h;氨氮、总氮去除率预测值分别为98.4%、83.2%,预测值与实测值吻合。响应曲面法用于优化曝气参数对人工湿地脱氮效能影响具有可行性,可实现间歇增氧人工湿地脱氮效能的准确预测。

关键词(KeyWords)： 人工湿地;脱氮;间歇;曝气;响应曲面法

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(51408570,51978636);; 中央高校基本科研业务费专项(201964005)资助~~

作者(Author): 宋维星,周衍平,陈旭,李恩,季军远

DOI: 10.16441/j.cnki.hdxb.20200045

参考文献(References)：

• [1] 魏成,刘平,秦晶,等.不同基质和不同植物对人工湿地净化效率的影响[J].生态学报,2008,28(8):3691-3697.Wei C,Liu P,Qin J,et al.Effects of substrates and plants on purification efficiency of constructed wetland[J].Acta Ecologica Sinica,2008,28(8):3691-3697.
• [2] Huett D O,Morris S G,Smith G,et al.Nitrogen and phosphorus removal from plant nursery runoff in vegetated and unvegetated subsurface flow wetlands[J].Water Research,2005,39(14):3259-3272.
• [3] 李胜男,崔丽娟,宋洪涛,等.不同湿地植物土壤氮、磷去除能力比较[J].生态环境学报,2012,21(11):1870-1874.Li S N,Cui L J,Song H T,et al.Comparison on purification capacity of soil nitrogen and phosphorus in different wetland plants[J].Ecology and Environmental Sciences,2012,21(11):1870-1874.
• [4] Park J B,Craggs R J,Tanner C C,et al.Eco-friendly and low-cost Enhanced Pond and Wetland (EPW) system for the treatment of secondary wastewater effluent[J].Ecological Engineering,2018,120:170-179.
• [5] 潘傲,张智,孙磊,等.种植不同植物的表面流人工湿地净化效果和微生物群落差异分析[J].环境工程学报,2019,13(8):1918-1929.Pan A,Zhang Z,Sun L.et al.Purification effects and microbial community differences of the surface-flow constructed wetlands with different vegetation plantation[J].Chinese Journal of Environmental Engineering,2019,13(8):1918-1929.
• [6] Zhuang L L,Yang T,Zhang J,et al.The configuration,purification effect and mechanism of intensified constructed wetland for wastewater treatment from the aspect of nitrogen removal:A review[J].Bioresource Technology,2019,doi.org/10.1016/j.biortech.2019.122086.
• [7] Liu H,Hu Z,Zhang Y.Microbial nitrogen removal of ammonia wastewater in poly (butylenes succinate)-based constructed wetland:effect of dissolved oxygen[J].Applied Microbiology and Biotechnology,2018,102(21):9389-9398.
• [8] 王玮,丁怡,王宇晖,等.人工湿地增氧技术在污水脱氮中的应用[J].工业水处理,2014,34(8):1-5.Wang W,Ding Y,Wang Y H,et al.Application of aeration technology to nitrogen removal in constructed wetlands[J].Industrial Water Treatment,2014,34(8):1-5.
• [9] Zhong F,Wu J,Dai Y R,et al.Bacterial community analysis by PCR-DGGE and 454-pyrosequencing of horizontal subsurface flow constructed wetlands with front aeration[J].Environmental Biotechnology,2015,99(3):1499-1512.
• [10] Wu S B,Lei M,Lu Q M.et al.Treatment of pig manure liquid digestate in horizontal flow constructed wetlands:Effect of aeration[J].Engineering in Life Sciences,2016,16(3):263-271.
• [11] 丁怡,唐海燕,宋新山,等.调控碳氧水平促进人工湿地脱氮的研究进展[J].水处理技术,2019,45(6):19-22.Ding Y,Tang H Y,Song X S,et al.Research progress in regulating carbon and oxygen levels of constructed wetlands for promoting nitrogen removal from wastewater[J].Technology of Water Treatment,2019,45(6):19-22.
• [12] Montgomery D C.Design and Analysis of Experiments[M].9th edition.New York:John Wiley & Sons,2018.
• [13] 张千,吉芳英,徐璇.响应曲面法在反硝化生物滤池运行参数优化中的应用[J].环境科学研究,2015,28(7):1138-1144.Zhang Q,Ji F Y,Xu X.Optimization of denitrification biofilter process using response surface methodology[J].Research of Environmental Sciences,2015,28(7):1138-1144.
• [14] 魏炜,孙舶洋,潘俊,等.响应曲面法对玉米秸秆稀酸水解还原糖条件的优化[J].沈阳建筑大学学报(自然科学版),2019,35(6):2095-1922.Wei W,Sun B Y,Pan J,et al.Optimization of corn straw cellulose dilute acid hydrolytic into reducing sugar by response surface methodology[J].Journal of Shenyang Jianzhu University(Natural Science) ,2019,35(6):2095-1922.
• [15] 万继腾,王正阳,刘邦海,等.响应曲面法和人工神经网络模型对电催化氧化磺胺甲恶唑条件的优化[J].中国海洋大学学报(自然科学版),2019,49(8):66-74.Wan J T,Wang Z Y,Liu B H,et al.Modeling and optimization of sulfamethoxazole treatment by electrocatalytic oxidationusing response surface methodology and artificial neural network approaches[J].Periodical of Ocean University of China,2019,49(8):66-74.
• [16] 李丽,王全金,胡常福,等.响应面法在复合垂直流人工湿地对村镇污水脱氮优化设计中的应用[J].环境污染与防治,2014,36(2):27-31.Li L,Wang Q J,Hu C F,et al.Denitrification orthogonal analysis of integrated vertical-flow constructed wetland based on response surface methodology[J].Environmental Pollution & Control,2014,36(2):27-31.
• [17] 国家环境保护总局,水和废水监测分析方法编委会.水和废水监测分析方法[M].第四版.北京:中国环境科学出版社,2002.Chinese NEPA.Water and Wastewater Monitoring Methods[M].Fourth ed.Beijing:Chinese Environmental Science Publishing Press,2002.
• [18] Swapnila R,Shubhalakshmi S,Suvendu M.et al.Chemically reduced tea waste biochar and its application in treatment of fluoride containing wastewater:Batch and optimization using response surface methodology[J].Process Safety and Environmental Protection,2018,116:553-563.
• [19] Gan C Y,Aishah A F.Extraction of antioxidant pectic-polysaccharide from mangosteen (Garcinia mangostana) rind:Optimization using response surface methodology[J].Carbohydrate Polymers,2011,83(2):600-607.
• [20] Yang P,Chen H,Liu Y W.et al.Application of response surface methodology and desirability approach to investigate and optimize the jet pump in a thermoacoustic Stirling heat engine[J].Applied Thermal Engineering,2017,127(12):1005-1014.
• [21] 赵剑斐,张毅博,黄涛,等.基于响应曲面法的餐厨垃圾与剩余污泥混合厌氧发酵工艺优化[J].安全与环境学报,2019,19(4):1316-1322.Zhang J F,Zhang Y B,Huang T,et al.Anaerobic co-digestion processing optimization for the food waste and sewage sludge based on response surface method[J].Journal of Safety and Environment,2019,19(4):1316-1322.
• [22] Das S,Mishra S.Box-Behnken statistical design to optimize preparation of activated carbon from Limonia acidissima shell with desirability approach[J].Journal of Environmental Chemical Engineering,2017,5(1):588-600.
• [23] Akkaya G K,Erkan H S,Sekman E,et al.Modeling and optimizing Fenton and electro-Fenton processes for dairy wastewater treatment using response surface methodology[J].International Journal of Environmental Science & Technology,2019,16:2343-2358.
• [24] Fan J L,Zhang B,Zhang J.et al.Intermittent aeration strategy to enhance organics and nitrogen removal in subsurface flow constructed wetlands[J].Bioresource Technology,2013,141(8):117-122.
• [25] Han B C,Jiang W L,Zhang Y.et al.Profile of organic carbon and nitrogen removal by a continuous flowing conventional activated sludge reactor with pulse aeration[J].Process Safety and Environmental Protection,2018,117(7):439-445.
• [26] Fan J L,Liang S,Zhang B.et al.Enhanced organics and nitrogen removal in batch-operated vertical flow constructed wetlands by combination of intermittent aeration and step feeding strategy[J].Environmental Science and Pollution Research,2013,20(4):2448-2455.
• [27] 汪健,李怀正,甄葆崇,等.间歇曝气对垂直潜流人工湿地脱氮效果的影响[J].环境科学,2016,37(3):980-987.Wang J,Li Z H,Zhen B C.et al.Effect of aeration on pollutants removal,biofilm activity and protozoan abundance in conventional and hybrid horizontal subsurface-flow constructed wetlands[J].Environmental Science,2016,37(3):980-987.
• [28] Enrica U,Theodore H R,Robert H M.Intermittent aeration to improve wastewater treatment efficiency in pilot-scale constructed wetland[J].Science of the Total Environment,2016,559(7):212-217.
• [29] Wu S B,Peter K,Hans B.et al.Development of constructed wetlands in performance intensifications for wastewater treatment:A nitrogen and organic matter targeted review[J].Water Research,2014,57:40-55.

文章评论(Comment)：