自抛光防污涂层的水渗透特性及其对抛光速率的影响研究Study on Water Penetration Characteristics of Self-Polishing Antifouling Coatings and Their Effect on Polishing Rates
张焕娟,丛巍巍,张凯,苏荣国,桂泰江
摘要(Abstract):
本文采用电化学阻抗谱法(EIS)对比分析了水在两种商业化丙烯酸硅自抛光防污涂层A1和A2中的渗透行为,并通过动态模拟实验测试了两种涂层在3.5%人工海水中的抛光速率。EIS测试结果表明,水在两种丙烯酸硅自抛光防污涂层中的渗透均呈典型的Fick扩散,进而拟合计算得到涂层A1的饱和吸水体积百分率约为11.5%,涂层A2的饱和吸水体积百分率约为20%。动态模拟实验表明防污涂层A1在人工海水中的抛光速率为0.15μm/d,涂层A2的抛光速率为0.26μm/d。饱和吸水体积百分率较大更有利于丙烯酸硅树脂水解,抛光速率更快。
关键词(KeyWords): 自抛光防污涂层;电化学阻抗谱;水渗透;抛光速率
基金项目(Foundation): 国家自然科学基金委员会-山东省人民政府联合基金项目(U2006219);; 国防基础科研计划项目(JCKY2021513B001)资助~~
作者(Author): 张焕娟,丛巍巍,张凯,苏荣国,桂泰江
DOI: 10.16441/j.cnki.hdxb.20220490
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